Frontispiece: Spotlight on Photoinduced Aryl Migration Reactions
نویسندگان
چکیده
Rearrangement reactions are a very powerful tool for the conversion of simple substrates into highly functionalized products in organic chemistry. In combination with an attractive initiation process, such as visible-light catalysis, these particularly powerful. Read more about recent progress on aryl migration reactions, focusing especially Smiles rearrangement and related Review by E. Brachet et al. page 3581.
منابع مشابه
"One-pot" two-step synthesis of aryl sulfur compounds by photoinduced reactions of thiourea anion with aryl halides.
[reaction: see text]. The photoinduced reactions of aryl halides with the thiourea anion afford arene thiolate ions in DMSO. These species without isolation, and by a subsequent aliphatic nucleophilic substitution, S(RN)1 reaction, oxidation, or protonation, yield aryl methyl sulfides, diaryl sulfides, diaryl disulfides, and aryl thiols with good yields (50-80%). This is a simple and convenient...
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ژورنال
عنوان ژورنال: Chemistry: A European Journal
سال: 2021
ISSN: ['0947-6539', '1521-3765']
DOI: https://doi.org/10.1002/chem.202181161